Surface layering in liquid gallium: An X-ray reflectivity study.

نویسندگان

  • Regan
  • Kawamoto
  • Lee
  • Pershan
  • Maskil
  • Deutsch
  • Magnussen
  • Ocko
  • Berman
چکیده

Surface-induced atomic layering in liquid gallium has been observed using x-ray reflectivity, ultrahigh vacuum conditions, and sputtered clean surfaces. Reflectivity data, collected on a supercooled liquid sample to momentum transfers as large as qz ­ 3.0 Å21, exhibit a strong maximum near 2.4 Å21 indicating a layer spacing that is comparable to its atomic dimensions. The amplitude of the electron density oscillations decays with a characteristic length of 6 Å. This is unexpectedly twice that of recent results for Hg, and the difference may be related to covalent bonding or supercooling.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Capillary-wave roughening of surface-induced layering in liquid gallium.

The temperature dependence of surface-induced atomic layering in liquid gallium has been investigated with x-ray reflectivity. The prominent layering peak at qz52.4 Å 21 decreases dramatically upon heating from 22 to 170 °C, but its width stays, unexpectedly, unchanged. The decrease is traced to the temperature dependence of capillary-wave induced surface roughness. The constant width indicates...

متن کامل

X-ray studies of atomic layering at liquid metal surfaces

Surface-induced layering has been observed in liquid gallium and mercury using X-ray reflectivity. The specular reflectivity R(q,) has been measured to wavevector transfers as large as q, = 3.0 A-‘. For Ga, the only major deviations from pesnel theory R, are near q, = 2.4 A-‘, where there is a peak in the ratio R/R,. For Hg, there is a broad peak near 2.15 A-‘. The data have been collected on a...

متن کامل

Surface structure of liquid metals and the effect of capillary waves: X-ray studies on liquid indium

We report x-ray reflectivity ~XR! and small-angle off-specular diffuse-scattering ~DS! measurements from the surface of liquid indium close to its melting point of 156 °C. From the XR measurements we extract the surface structure factor convolved with fluctuations in the height of the liquid surface. We present a model to describe DS that takes into account the surface structure factor, thermal...

متن کامل

X-ray reflectivity study of temperature-dependent surface layering in liquid Hg

We report x-ray reflectivity measurements of liquid mercury between 236 °C and 125 °C. The surface structure can be described by a layered density profile convolved with a thermal roughness sT . The layering has a spacing of 2.72 Å and an exponential decay length of 5.0 Å. Surprisingly, sT is found to increase considerably faster with temperature than the AT behavior predicted by capillary wave...

متن کامل

X-ray reflectivity measurements of surface layering in liquid mercury.

The surface normal structure of the mercury liquid-vapor interface has been investigated by measuring the x-ray reflectivity out to a momentum transfer of qz ­ 2.5 Å . The results provide direct experimental proof of surface layering in liquid metals. The layer spacing is given by the atomic dimensions of the Hg atoms. The minimum layer width agrees well with the predictions of capillary wave t...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Physical review letters

دوره 75 13  شماره 

صفحات  -

تاریخ انتشار 1995